Product ID:16440 GRAY ZENTHANE PLUS, MIL-PRF-85285C, TYPE I
MSDS Date:08/31/1998
FSC:8010
NIIN:01-285-3046
Status Code:A
MSDS Number: CLKNG

HENTZEN COATINGS INC

6937 WEST MILL ROAD
MILWAUKEE, WI 53218
US

Emergency Phone: 800-424-9300

Info Phone: 414-353-4200

Preparer: ERNEST CARTER

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

HOMOPOLMER OF HEXAMETHYLENE DIISOCYANATE

CAS: 28182-81-2

RTECS: NQ9170000

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.034 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE

CAS: 95-63-6

RTECS: DC3325000

OSHA PEL 25 PPM

AROMATIC HYDROCARBONS

CAS: 64742-95-6

RTECS: WF3400000

METHYL AMYL KETONE

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY CAUSE THE
FOLLOWING EFFECTS: NOSE, THROAT AND RESPIRATORY TRACT, IRRITATION.
ALLERGIC RESPIRATORY REACTION. MAY CAUSE LUNG DAMAGE. EYE AND SKIN
IRRITATION. ALLERGIC SKIN REACTI ON.
Explanation of Carcinogenicity:THIS PRODUCT HAS NOT BEEN TESTED AS A
WHOLE FOR CARCINOGENICITY. CONTAINS CARBON BLACK WHICH HAS BEEN
LISTED BY IARC AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B) BASED UPON
LABORATORY ANIMAL INHALATION S TUDIES.
Effects of Overexposure:EYE CONTACT: WITH LIQUID VAPORS CAUSING
TEARING, REDDENING AND SWELLING ACCOMPANIED BY A STINGING. SKIN
CONTACT: SYMPTOMS MAY BE REDDENING, RASH, SWELLING, SCALING OR
BLISTERING. INHALATION: STEPS IF SEVERE OVEREXPOSURE IS CONTINUED:
HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION OR UNCONSCIOUSNESS.
INGESTION: CAN RESULT IN CORROSIVE ACTION IN THE MOUTH, STOMACH
TISSUE AND DIGESTIVE TRACT
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; SKIN ALLERGIES AND ECZEMA.

First Aid:EYE CONTACT: FLUSH WITH LOW PRESSURE LUKE WARM RUNNING WATER
FOR AT LEAST 15 MINUTES. SKIN CONTACT: WASH AFFECTED AREAS
THOROUGHLY WITH SOAP AND WATER. INMHALATION: MOVE TO AN AREA FREE
FROM RISK OF FURTHER EXPOSURE. INGESTION: CALL A PHYSICIAN
IMMEDIATELY.

Flash Point Method:CALC
Flash Point:=7.8C, 46.F
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:.90
Upper Limits:8.70
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF
CONTAINED BREATHING APPARATUS SHOULD BE WORN.

Spill Release Procedures:COLLECT MATERIAL IN OPEN CONTAINERS ADD
FURTHER AMOUNTS OF DECONTAMINATION SOLUTION.

Handling and Storage Precautions:PRECAUTIONS MUST BE TAKEN SO THAT
PERSONS HANDLING THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT
CONTACT THE EYES OR SKIN. STORAGE: KEEP CONTAINERS TIGHTLY CLOSED
AND PROTECT FROM MOISTURE CONTAMI NATION.

Respiratory Protection:AIR-PURIFYING CHEMICAL CARTRIDGE RESPIRATORS.
Ventilation:EXHAUST VENTILATION.
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:SPLASH GUARDS OR SIDE SHIELDS. A FULL FACE SHIELD MAY BE
APPROPRIATE.
Other Protective Equipment:SAFETY SHOWERS AND EYE WASH STATIONS SHOULD
BE AVAILABLE.
Supplemental Safety and Health

Boiling Pt:B.P. Text:LO-213.00-HI-418 F
Vapor Pres:27.800
Vapor Density:4.800
Spec Gravity:1.2960
VOC Pounds/Gallon:440
VOC Grams/Liter:3.68
Evaporation Rate & Reference:2.3000 (N-BUTYL ACETATE=1
Solubility in Water:REACTS WITH WATER
Appearance and Odor:LIQUID OPAQUE LIQUID SOLVENT ODOR
Percent Volatiles by Volume:51.857

Stability Indicator/Materials to Avoid:YES
EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES OR
OTHER ACTIVE MATERIALS.CARBON DIOXIDE GAS COULD BUILD UP IN THE
CONTAINER RESULTING IN RAPID DEPRESSURIZATION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
CHLORINE, HYDROGEN CHLORIDE AND POSSIBLE CYANIDE, HEXAMCTHYLENE
DIISOCYANATE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LAWS
AND REGULATIONS.

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